Aging skin gets thinner and drier. It makes fewer of its own fats and repairs itself more slowly. So it loses water faster and gets irritated more easily.
Its surface gets less acidic. The review says this slows the enzymes that build the barrier's fats. It also speeds up enzymes that loosen the outer layer, weakening the barrier further.
Its bacteria shift. A less acidic surface favors bacteria that like those conditions and can add to irritation. Protective resident bacteria become less common.
Nerves become more sensitive. The authors say a weak barrier, shifted bacteria and busier enzymes add up. Together, they make the skin's nerves quicker to send itch signals.
They suggest that bringing skin back to its normal acidity is a logical way to approach this kind of itch.